Optimisation of graphene oxide–iron oxide nanocomposite in heterogeneous Fenton-like oxidation of Acid Orange 7

Nor Aida Zubir Christelle Yacou 1, 2 Xiwang Zhang João C. Diniz da Costa 3
1 University of Queensland [Brisbane]
2 COVACHIM- M2E - Connaissance et Valorisation : Chimie des Matériaux, Environnement, Energie
3 FIM2Lab - The University of Queensland, FIM2Lab – Functional Interfacial Materials and Membrane Laboratory, School of Chemical Engineering, Brisbane, QLD 4067, Australia
University of Queensland [Brisbane]
Abstract : Well-dispersed iron oxide nanoparticles supported onto graphene oxide sheets (i.e. GO-Fe3O4 nanocomposite) were synthesised and used as heterogeneous Fenton-like catalyst for the degradation of Acid Orange 7 dye (AO7). The reaction was systematically investigated under various experimental conditions such as nanocomposite dosage, pH, temperature, oxidant and dye concentrations. Best results showed a fast 80% degradation in ∼20 min, whilst ∼98% of AO7 was successfully removed after 180 min of reaction time. The degradation kinetics of AO7 was most influenced by pH and temperature, and can be described by a pseudo-first-order reaction following the Langmuir-Hinshelwood mechanism. Analysis of the spent nanocomposite suggested that the phase of iron oxide nanoparticles remained unchanged whilst minor pore volume losses occurred via carbon deposition and/or re-stacking of GO sheets. © 2014 Elsevier Ltd.
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Journal articles
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https://hal.univ-antilles.fr/hal-01683206
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Submitted on : Friday, January 12, 2018 - 9:51:51 PM
Last modification on : Tuesday, April 16, 2019 - 8:28:02 PM

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Nor Aida Zubir, Christelle Yacou, Xiwang Zhang, João C. Diniz da Costa. Optimisation of graphene oxide–iron oxide nanocomposite in heterogeneous Fenton-like oxidation of Acid Orange 7. Journal of Environmental Chemical Engineering, Elsevier, 2014, 2 (3), pp.1881 - 1888. ⟨10.1016/j.jece.2014.08.001⟩. ⟨hal-01683206⟩

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