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The sacrificial role of graphene oxide in stabilising a Fenton-like catalyst GO–Fe 3 O 4

Nor Aida Zubir 1 Christelle Yacou 1, 2 Julius Motuzas 3 Xiwang Zhang Xiu Song Zhao João C. Diniz da Costa 4
1 University of Queensland [Brisbane]
2 COVACHIM- M2E - Connaissance et Valorisation : Chimie des Matériaux, Environnement, Energie
3 IEM - Institut Européen des membranes
4 FIM2Lab - The University of Queensland, FIM2Lab – Functional Interfacial Materials and Membrane Laboratory, School of Chemical Engineering, Brisbane, QLD 4067, Australia
University of Queensland [Brisbane]
Abstract : Owing to the electron donor-acceptor properties of GO, the active sites (≡Fe2+) of Fe3O4 are not oxidised (≡Fe3+) in the heterogeneous Fenton-like reaction. GO plays a sacrificial role via the oxidation of (C=C) carbon domains, and transferring electrons to Fe3O4. Therefore, GO-Fe3O4 confers superior catalytic efficiency, recyclability and longevity, otherwise not available in Fe3O4. © The Royal Society of Chemistry 2015.
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https://hal.univ-antilles.fr/hal-01683211
Contributor : Christelle Yacou <>
Submitted on : Friday, January 12, 2018 - 9:59:37 PM
Last modification on : Tuesday, May 28, 2019 - 2:18:04 PM

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UNIV-AG | CNRS | IEM | INC-CNRS | CHIMIE | UNIV-MONTPELLIER | COVACHIM-M2E

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Nor Aida Zubir, Christelle Yacou, Julius Motuzas, Xiwang Zhang, Xiu Song Zhao, et al.. The sacrificial role of graphene oxide in stabilising a Fenton-like catalyst GO–Fe 3 O 4. Chemical Communications, Royal Society of Chemistry, 2015, 51 (45), pp.9291 - 9293. ⟨10.1039/c5cc02292d⟩. ⟨hal-01683211⟩

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